Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

GNSS多天线基线网单历元模糊度同步解算法     

汤佳明  柴艳菊  闻德保  欧吉坤 《大地测量与地球动力学》2019,39(3):262-268

提出多天线基线网单历元模糊度同步解算法，其具体实现步骤为：1）根据宽巷组合模糊度易于固定的优点，采用附加已知基线长度约束法同步解算各基线的宽巷模糊度，得到dm~cm级精度的近似基线分量；2）将解算得到的各近似基线分量作为约束，同步解算各基线的基频模糊度，以获取mm级精度的基线矢量。该方法的关键在于检验各历元宽巷模糊度解算的正确性，以获取可靠的近似基线分量，为解算各基线的基频模糊度提供准确的基线先验信息。由于动态情况下各历元观测信息比较少，单纯依赖ratio检验不可靠，提出结合基线误差、单位权中误差、基线网模糊度闭合环及ratio值等对多组宽巷模糊度进行检验，避免ratio值设置不当导致模糊度检验中发生纳伪和弃真问题。实测数据结果证明，该处理方法使得模糊度解算的成功率提高1%~2%，可以获取移动平台更丰富的导航信息，提高其服务能力。  相似文献   

利用稳定同位素(15N)示踪技术研究浮游藻类氮素吸收速率特征     

韩菲尔  赵中华  李大鹏  张路 《海洋与湖沼》2019,50(4):811-821

浮游藻类对溶解态氮的吸收同化是湖泊氮生物循环和水体富营养化发生机制探讨的关键环节。本文通过~(15)N稳定同位素添加实验以铜绿微囊藻(Microcystis aeruginosa)、海链藻(Thalassiosira sp.)、卡德藻(Tetraselmis sp.)、剧毒卡尔藻(Karlodinium veneficum)以及盐水隐藻(Rhodomonas salina)为研究对象,从浮游藻类氮素吸收时间、营养盐基质以及藻种差异三个方面研究五种藻类对铵氮(NH_4~+-N)、硝氮(NO_3~--N)、尿素氮(Urea-N)三种形态氮的吸收特征。研究发现:(1)浮游藻类对三种形态氮的吸收均在1h时吸收速率最高,其氮素吸收过程为快速吸收。(2)浮游藻类优先吸收还原态氮,其中NH_4~+-N吸收速率最高,当培养周期为1d和4d时浮游藻类对NH_4~+-N吸收速率的均值分别为4.05和4.15μmol/(L·h);浮游藻类对Urea-N吸收相对偏好系数为25.18—713.42,表现出对小分子溶解态有机氮的特定偏好性。(3)不同藻种对氮素吸收具有不同特征,其中,剧毒卡尔藻对三种形态氮的吸收速率均为最高,而铜绿微囊藻的吸收速率均为最低;不同藻种不同培养时间氮素吸收速率差异与浮游藻类生长周期等特性有关。不同浮游藻类对不同形态氮素表现出吸收特异性,对水体氮负荷和浮游藻类水华优势种形成将产生重要影响。  相似文献   

基于噪声谱比法的内蒙古西部地区台站场地响应研究     

张珂  王鑫  王树波  张红才  宋晓燕 《大地测量与地球动力学》2020,40(6):646-651

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。  相似文献   

黏土水泥浆材特性的试验研究     

邱浩浩 《地质与勘探》2020,56(6):1272-1277

黏土水泥浆材是采空区处治的优选注浆材料，但目前关于优化浆材配比的研究较少。针对毕威高速公路水塘隧道出口段采空区处治工程，提出采用黏土水泥浆液进行注浆处理，并进行室内试验研究，得到了不同配比浆液的凝结时间、结石率、结石密度、结石体抗压强度、渗透系数及冲蚀率等性能指标。试验结果表明，固相比较低的浆液凝结时间较短，抗压强度较高，渗透系数较大；随原浆比重增加，浆液的凝结时间缩短，强度提高且渗透系数降低；偏铝酸钠可有效缩短浆液的凝结时间；最终确定了黏土水泥浆材的配比和原浆比重。本次研究可为高速公路下伏采空区的注浆治理提供设计依据。  相似文献   

伏牛山地区森林生态系统服务权衡/协同效应多尺度分析   总被引：3，自引：0，他引：3  

张静静  朱文博  朱连奇  李艳红 《地理学报》2020,75(5):975-988

森林生态系统服务权衡与协同研究已成为当前相关学科的研究热点和前沿,对服务权衡与协同关系的多尺度分析有助于更加有效地实施森林资源管理。综合森林类型图、NDVI、气象和土壤等多源数据,借助CASA模型、InVEST 3.2模型和ArcGIS 10.2软件,开展伏牛山地区森林生态系统服务评估,运用空间叠置方法从多个空间尺度（区域、南北坡、垂直带）探讨服务权衡与协同效应。结果表明：① 研究区森林生态系统平均蓄积量为49.26 m ³/hm ²,碳密度为156.94 t/hm ²,供水深度为494.46 mm,土壤保持量为955.4 t/hm ²,生境质量指数为0.79。② 区域尺度上,28.79%的森林服务之间存在高协同效应,10.15%的森林存在低协同效应,61.06%的森林存在强权衡和弱权衡效应。③ 南北坡尺度上,南坡服务之间的协同关系优于北坡。垂直带尺度上,南坡中山落叶阔叶林带（SIII）服务之间协同关系最好,北坡低山落叶阔叶林带（NI）协同关系最差。  相似文献   

Modeling spatially non-stationary land use/cover change in the lower Connecticut River Basin by combining geographically weighted logistic regression and the CA-Markov model   总被引：2，自引：0，他引：2  

Hui Wang  Scott R. Stephenson  Shijin Qu 《International journal of geographical information science》2019,33(7):1313-1334

Simulating land use/cover change (LUCC) and determining its transition rules have been a focus of research for several decades. Previous studies used ordinary logistic regression (OLR) to determine transition rules in cellular automata (CA) modeling of LUCC, which often neglected the spatially non-stationary relationships between driving factors and land use/cover categories. We use an integrated geographically weighted logistic regression (GWLR) CA-Markov method to simulate LUCC from 2001–2011 over 29 towns in the Connecticut River Basin. Results are compared with those obtained from the OLR-CA-Markov method, and the sensitivity of LUCC simulated by the GWLR-CA-Markov method to the spatial non-stationarity-based suitability map is investigated. Analysis of residuals indicates better goodness of fit in model calibration for geographically weighted regression (GWR) than OLR. Coefficients of driving factors indicate that GWLR outperforms OLR in depicting the local suitability of land use/cover categories. Kappa statistics of the simulated maps indicate high agreement with observed land use/cover for both OLR-CA-Markov and GWLR-CA-Markov methods. Similarity in simulation accuracy between the methods suggests that the sensitivity of simulated LUCC to suitability inputs is low with respect to spatial non-stationarity. Therefore, this study provides critical insight on the role of spatial non-stationarity throughout the process of LUCC simulation.  相似文献   

An efficient and robust approach to predict ship self-propulsion coefficients     

《Applied Ocean Research》2019

Achieving a reliable and accurate numerical prediction of the self-propulsion performance of a ship is still an open problem that poses some relevant issues. Several CFD methods, ranging from boundary element methods (BEM) to higher-fidelity viscous Reynolds averaged Navier–Stokes (RANS) based solvers, can be used to accurately analyze the separate problems, i.e. the open water propeller and the hull calm water resistance. However, when the fully-coupled self-propulsion problem is considered, i.e. the hull advancing at uniform speed propelled by its own propulsion system, several complexities rise up. Typical flow simplifications adopted to speed-up the simulations of the single analysis (hull and propeller separately) lose their validity requiring a more complex solver to tackle the fully-coupled problem. The complexity rises up further when considering a maneuver condition. This aspect increases the computational burden and, consequently, the required time which becomes prohibitive in a preliminary ship design stage.The majority of the simplified methods proposed in literature to include propeller effects, without directly solve the propeller flow, in a high-fidelity viscous solver are not able to provide all the commonly required self-propulsion coefficients. In this work, a new method to enrich the results from a body force based approach is proposed and investigated, with the aim to reduce as much as possible the computational burden without losing any useful result. This procedure is tested for validation on the KCS hull form in self-propulsion and maneuver conditions.  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

唐山地区波速比变化特征研究     

王亚茹  宋昭  刘晓丹  郭蕾  王妍  王时  宫猛  王想 《大地测量与地球动力学》2019,39(7):686-690

选取唐山地区2008~2018年震相数据，利用单台多震和达法和多台多震和达法分别计算波速比，结合研究区内的地震活动对波速比的变化特征进行研究。结果显示，多台多震和达法得到的波速比结果较为稳定，而单台多震和达法得到的结果变化幅度大，显示更多细节；唐山地区ML≥4.5地震发生前单台波速比存在不同程度的异常，异常台站的方位与地震具有一定的对应性。  相似文献